Tuesday, April 3, 2018

Chapter 15.2 - Some important Organic compounds

In the previous section, we completed a discussion on combustion  and thermal cracking. In this section we will see some important organic compounds.

Alcohols

• We have learned the nomenclature details about alcohols in the previous chapter. 
• They contain the OH functional group.  
• CHOH (Methanol) and  CHCHO(Ethanol) are two important alcohols.
• Methanol is commonly known as wood spirit
• Ethanol is commonly known as grape spirit
■ First we will see methanol in detail:
Uses of methanol
1. Methanol is used as a solvent in the manufacture of paint
2. It is also used as a reactant in the manufacture of varnish and formalin
• So it is a very valuable industrial substance. It is very poisonous too.

Industrial preparation of methanol
• Methanol is industrially prepared by the reaction between carbon monoxide with hydrogen in the presence of catalysts. The equation is shown below:

Note that 3 items are required for the reaction:
(i) Catalyst
(ii) Temperature of 573 k. (Details about the units of temperature can be seen here)
(iii) Pressure of 200 atm (Details about pressure can be seen here)

■ Next we will see ethanol:
Uses of ethanol
1. Ethanol is used as an organic solvent 
2. It is used in the manufacture of various organic compounds and paints. 
3. It can also be used as a fuel by itself or in combination with other compounds.

Industrial preparation of ethanol

1. During the manufacture of sugar, we get a liquid mixture of sugar crystals. 
• That is., a liquid containing crystals of sugar
2. When the solid sugar crystals are removed, a liquid is left behind. 
• This liquid is a concentrated solution of sugar. 
• This concentrated solution of sugar is called molasses
3. This molasses is diluted and then fermented. 
• Fermentation is done by adding yeast. The process of fermentation lasts for a few days. 
• During the fermentation, some reactions occur due to the presence of enzymes in the yeast. 
• The enzymes are: Invertase and Zymase
The reactions are shown below:

4. The reaction takes place in stages:
• First the sugar is converted into glucose and fructose. 
    ♦ This is accomplished with the help of the enzyme invertase
    ♦ Note that glucose and fructose have the same molecular formula. 
    ♦ But they have different structural formulae
• Then the gucose and fructose are converted into ethanol. 
    ♦ This is accomplished with the help of the enzyme zymase
5. The ethanol thus obtained will be about 8-10% strong. 
• That is., if there are a total of 100 molecules in a sample, only 8 to 10 of them will be ethanol molecules. 
• This ethanol is called wash
6. Wash is subjected to fractional distillation. Some basics about fractional distillation can be seen here.
• By this process, we get 95.6% strong ethanol solution. It is known as rectified spirit.
7. Rectified spirit is a very important industrial substance. So it would be produced on a large scale.
• This rectified spirit meant for industrial purpose should not be used as a beverage. 
• To prevent it's use as a beverage, poisonous substances are added to those ethanol which are meant for industrial purposes. 
• This ethanol is called denatured spirit.
8. 99.5% ethanol is known as absolute alcohol
• A mixture of absolute alcohol and petrol is known as power alcohol. It is used as fuel in automobiles.
9. What we saw above is the production of ethanol from molasses. 
• Ethanol can be manufactured from starchy substances like barley, rice, tapioca etc., also.


Carboxylic acids

These are compounds containing carboxylic acid group (COOH). We have seen their nomenclature details in the previous chapter. Some examples are:
1. IUPAC name: Methanoic acid
• Common name: Formic acid
• Formula:  H ㅡCOOH 
• Structural formula: See fig.15.20(a) below 
2. IUPAC name: Ethanoic acid 
• Common name: Acetic acid
• Formula:  CHㅡCOOH 
• Structural formula: See fig.15.20(b) below
3. IUPAC name: Propanoic acid
• Common name: Propionic acid
• Formula:  CHCHㅡCOOH 
• Structural formula: See fig.15.20(c) below
Fig.15.20
• Many substances obtained from nature contains carboxylic acids. For example:
• The product obtained as a result of the fermentation of fruits will contain Ethanoic acid (Acetic acid)
• About 5-8% strong ethanoic acid is called vinegar.
• Carboxylic acids are usually prepared by the oxidation of alcohols. 
    ♦ Vinegar can be prepared from ethanol in this way
• Carboxylic acids containing 12 or more carbon atoms are called fatty acids.

Industrial preparation of Ethanoic acid

• Ethanoic acid can be manufactured by treating methanol with carbon monoxide in the presence of catalyst. The reaction is shown below:

• Note that when the number of carbon atoms become 2, the 'meth' becomes 'eth'
• Vinegar can be obtained by the fermentation of ethanol in the presence of air using the bacteria acetobactor

Uses of ethanoic acid:
• In the manufacture of rayon
• In the rubber and silk industry
• Gives flavour to food items
• As a preservative

Esters

• Esters are obtained by the reaction between alcohols and carboxylic acids. 
• We have seen the details about both alcohols and carboxylic acids above. 
■ So let us see an example of a reaction between them:
• Consider a carboxylic acid: Ethanoic acid
• Consider a alcohol: Ethanol
• The equation of the reaction between them is shown below:
• Note how the two oxygen atoms come together
• From the structural formula of the product Ethyl ethanoate, it is clear that, the functional group in esters is:  ㅡCOO
• We have seen that fatty acids are carboxylic acids having 12 or more carbon atoms
    ♦ Palmitic acid and stearic acid are fatty acids
    ♦ Because they are carboxylic acids having 12 or more carbon atoms
• Consider an alcohol: Glycerol
    ♦ It reacts with palmitic acid and stearic acid. 
    ♦ The products are oils and fats. 
    ♦ Oils and fats are esters
Solved example 15.6:
Examine the structural formulae given below and identify the esters. Write the chemicals required for the manufacture of each of those esters.
1.  CHCH2ㅡCOOCH3  
2.  CHCH2ㅡCOOH
3.  CHCH2ㅡCOCH3    
4.  CHOH
5.  CHCH2CH2OH.
6.  CHㅡCOOH
7.  CHCH2CH2COOCH3  
Solution:
Esters contain the 'ㅡCOO' functional group. So (1) and (7) are esters
1.  CHCH2ㅡCOOCH3
• In the 'ㅡCOO', the CO comes from a carboxylic acid
• The second O comes from an alcohol
• So we can split it as: CHCH2ㅡCOOCH3  
• On the left side, we have 3 carbon atoms. So it indicates Propanoic acid
• On the right side, we have 1 carbon atom. So it indicates Methanol
• So the chemicals required are: Propanoic acid and methanol
7.  CHCH2CH2ㅡCOOCH3
• In the 'ㅡCOO', the CO comes from a carboxylic acid
• The second O comes from an alcohol
• So we can split it as: CHCH2CH2ㅡCOOCH3  
• On the left side, we have 4 carbon atoms. So it indicates Butanoic acid
• On the right side, we have 1 carbon atom. So it indicates Methanol
• So the chemicals required are: Butanoic acid and methanol

Aromatic compounds

Consider the aromatic compound shown in fig.15.21(a) below:
Fig.15.21
• It is the simplest aromatic compoundstructure. It's name is benzene
• It has 6 carbon atoms. These carbon atoms are arranged at the corners of a regular hexagon
• But each of those carbon atoms have only one hydrogen atom.
• So to satisfy the valency requirements, there should be 3 double bonds. 
• These double bonds will be arranged alternately. 
    ♦ That is., no two double bonds in the structure will come near each other.
■ So there are two possible ways to draw the structure
• In fig.a, the first double bond starts at top left   
• In fig.b, the first double bond starts at top right
■ A simple way for drawing the structures is shown in fig.15.22 below
Fig.15.22
Compounds of Benzene
• All aromatic compounds have a ring structure. 
• There are double bonds between alternate carbon atoms
• In benzene, each carbon atom has one hydrogen atom. 
• Any one of those hydrogen can be replaced by a functional group. 
• Thus we get different aromatic compounds. Some examples are shown in fig.15.23 below:
Fig.15.23
• These compounds have immense chemical and industrial significance. 
• Many useful substances can be prepared from them. 
• Coal tar obtained by the distillation of coal in the absence of air is the source of aromatic compounds.

In the next section, we will see some important applications of Chemistry

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Monday, April 2, 2018

Chapter 13.3 - Production of Aluminium and Copper

In the previous section, we saw the industrial production of steel. In this section, we will see the industrial production of aluminium and copper.

Industrial production of Aluminium

Extraction of Aluminium
• Aluminium is the most abundant metal on the earth's crust. 
• But it's reactivity is more than gold and silver. 
• So it is found in a combined state in nature. 
• A 'cost effective method to separate pure aluminium from it's ore' was discovered only in the nineteenth century. Until then aluminium was costlier than gold.
• The method is known as the Hall-Heroult process. It was discovered by two scientists Charles Martin Hall and Paul Heroult.
• Let us see the details of this process. We will write it in steps:
1. Bauxite (Al2O3.2H2O) is the ore of aluminium. 
• The chief impurity in it, is the silicon dioxide (SiO2
2. We know that any ore is to be powdered before it enters the first stage. It is true for bauxite also. So the bauxite is finely powdered.
• Stage 1 is the concentration of the powdered ore. 
• We have seen the different methods used for concentration. In the case of bauxite, leaching is used.
3. For that, the powdered bauxite is treated with hot concentrated NaOH solution. 
• Then the Al2O3 in the bauxite dissolves in the solution. 
• The impurities will not dissolve. So they are filtered off. 
4. But the aluminium that we want, is now in a dissolved form inside the solution. We want it back.
• Inside the solution, the aluminium exists as sodium aluminate (NaAlO2). 
5. So, to this solution, a little aluminium hydroxide (Al(OH)3) is added. 
• After that, the solution is diluted with water. 
• Then the Al gets separated from NaAlO2 and will precipitate as Al(OH)3
• This precipitate is filtered and washed. 
• Once we get this Al(OH)3, leaching is complete. 
6. Next step is to convert this hydroxide into the oxide. 
• For that, calcination is used. 
• The hydroxide is heated strongly. It decomposes to give the oxide. 
• The equation is: 2Al(OH)3 (s) ➙ Al2O3 (s) + H2O (l)
• Al2O3 is called alumina
7. So the second stage is also over. The third and final stage is refining. 
• We have to reduce the oxide Al2O3 into pure aluminium. 
8. The Al2O3 is so stable that carbon or carbon monoxide is not sufficient to reduce it. 
• We will need the 'most powerful reducing agent', which is electricity. 
• That is., we will need to conduct electrolysis to obtain pure aluminium from Al2O3.
9. We will have to melt Al2O3 into a liquid form. 
• This molten Al2O3 will be the electrolyte. 
10. But Al2O3 will not melt easily. Because it's melting point is very high. 
• But when heated after adding cryolite, the cryolite melts and Al2O3 dissolves in it. 
• Cryolite helps to achieve two things:
    ♦ Bring down the melting point of Al2O3 
    ♦ Increase the electrical conductivity of the molten mixture.
11. Consider the fig.13.8 below:
Fig.13.8
• The molten mixture is inside a steel tank 
    ♦ The steel tank has a carbon lining on the inner sides. 
    ♦ This carbon lining is the negative electrode. 
• Carbon rods act as positive electrodes. 
12. The Al2O3 exists as ions. Al3+ ions and O2- ions. 
• When electricity is passed through the electrodes, the positive Al3+ ions gets separated from the O2- ions and move towards the negative electrode. 
• There they accept electrons and get reduced to Al atoms. 
13. The negative O2- atoms move towards the positive electrodes. 
• There they donate the electrons and get oxidised to Oxygen atoms. 
• Thus oxygen is produced at the positive electrodes. 
• The positive electrodes are carbon rods. The newly produced oxygen reacts with the carbon rods. So these carbon rods will have to be replaced from time to time. 
14. The newly produced pure aluminium is in a molten state. 
• It is denser than the electrolyte. So it is collected at the bottom of the tank. 
• It is taken out through the plug.
• Thus the refining process is complete


Aluminium is a metal with many special properties:
• It is a light metal
• It has good thermal conductivity. So it is used for making cooking vessels  
• It has good electrical conductivity. So it is used for making electrical wires
• It has good metallic lustre. So it is used for making reflectors. See images here.
• It has great malleability. So it can be made into thin sheets.

Refining of copper

We have seen that there are 3 stages in the production of metals:
1. Concentration of ore 
2. Extraction of metals from the concentrated ore
3. Refining of the metals
• But in this section we are discussing only the refining of copper. Why is that? What about the first two stages?
Ans: We have already mentioned the first two stages related to copper.
• When we discussed froth floatation, we mentioned that copper pyrites is concentrated by that method
• When we discussed roasting, we mentioned that Cu2S is extracted by that method.
• So now we will see refining of copper
• Copper is a metal that is widely used in electrical appliances. 
• For such purposes, copper used must be very pure. Electrolytic method is used to obtain pure copper. Consider the fig.13.9 below:
Fig.13.9
1. 'Copper obtained during extraction', which contains many impurities is used as the positive electrode. We have seen the reason here
2. Pure copper is used as the negative electrode. 
3. Copper sulphate solution to which a little H2SOadded is used as the electrolyte. 
4.When the switch is turned on:
• At the positive electrode, the Cu2+ ions separates themselves from the impurities and go into the solution. 
• These positive ions are attracted towards the negative electrode. There they receive two electrons and become pure copper atoms. 
• The reaction taking place is: Cu2+ + 2e- ➙ Cu
5. This is a reduction reaction. 
• In any type of cell (galvanic cell or electrolytic cell), cathode is where reduction takes place.  So in our present case:
• The original pure metal piece used as the negative electrode is the cathode. 
• And the impure metal piece is the anode.
6. As more and more Cu2+ ions begin to leave the anode, the impurities cannot be bound together. 
• So The impurities disintegrate into smaller pieces and gets deposited below the anode. 
• This is called anode mud. Anode mud may contain valuable metals like gold or silver. 
7. The pure copper is removed from the cathode after a few days

Now we will see some solved examples:
Solved example 13.2
During the extraction of iron, a mixture of coke, limestone and haematite is added from the top into the blast furnace. What is the significance of adding limestone in the mixture?
Solution:
1. The calcium carbonate (in the form of limestone) which is supplied along with the haematite, will decompose into calcium oxide and carbon dioxide. 
The equation is: CaCO(s) ➙ CaO (s) + CO(g)
2. The calcium oxide (CaO) thus formed will combine with silicon dioxide (SiO2). 
• This SiO2 is the main impurity. It is sand. 
• The reaction between sand and CaO converts the sand into calcium silicate.
• The equation is: CaO (s) + SiO(s) ➙ CaSiO(s)
• Thus the sand is removed.
3. Sand (SiO2) is the gangue. It is acidic
• Calcium oxide (CaO) is the flux. It is basic
• The above two react to form the slag calcium silicate (CaSiO3).
4. We can remove the gangue only by converting it into slag
• To convert the gangue into slag, we need the flux CaO
• To obtain CaO, we need CaCO3. That is why we add limestone

Solved example 13.3
Which one does not belong to the group? Why?
(a) Leaching, Distillation, Froth floatation, Hydraulic washing
(b) Bauxite, Haematite, Clay, Cryolite 
Solution:
(a) Distillation does not belong to the group because it is a refining process
All others are concentration processes
(b) Haematite does not belong to the group because it is an ore of iron
All others are minerals of aluminium

Solved example 13.4
Match the following

A B C
1 Sulphide ore Bauxite Electrolysis
2 Ore of iron Zinc blende Calcination
3 Aluminium ore Calamine Blast furnace
4 Carbonate ore Haematite Froth floatation process

Solution:

A B C
1 Sulphide ore Zinc blende Froth floatation process
2 Ore of iron Haematite Blast furnace
3 Aluminium ore Bauxite Electrolysis
4 Carbonate ore Calamine Calcination


In the next chapter, we will see Nomenclature of organic compounds

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Sunday, April 1, 2018

Chapter 13.2 - Industrial Production of Iron

In the previous section, we saw the various stages in the production of metals. In this section, we will see how these stages are applied in the case of iron.

Industrial production of iron

We will write it in steps:
1. Haematite is the principal ore of iron.
• As we have seen in the previous sections, which ever be the metal, the ore has to be powdered.
• The 'concentration of the powdered ore' is the first stage.
2. In the case of haematite, we use the levigation method for the concentration. 
• As iron is heavier than the impurities, it will settle to the bottom of the tank. 
• The impurities will be washed away.
• So first stage is over
3. The second stage is the extraction of the metal from the concentrated ore. 
• We have seen that there are two steps to be completed for this. They are:
(a) Conversion of the ore into it's oxide.
(b) Reduction of the oxide
4. Let us see how they are accomplished in the case of iron:
(a) First we have to convert the iron into iron oxide. There are two methods available.
(i) Calcination and (ii) roasting. 
• In the case of iron, roasting is used. 
• Haematite is Fe2O3. So it already contains the oxide of iron. Even then, it is subjected to roasting.
• During roasting, impurities like sulphur, arsenic, phosphorus etc., are removed as their gaseous oxides. Water is also expelled. 
5. Next, we have to reduce the oxide.
• The haematite obtained after roasting will contain large quantities of silicon dioxide (sand). So we have to remove it to get the pure iron. The following procedure is used:
6. A mixture of roasted haematite, coke and lime stone (CaCO3) is fed into a blast furnace. See fig.13.7 below:
Fig.13.7
• Blast furnace is a huge steel furnace. 
• Steel cannot withstand the high temperature produced inside the furnace. 
• So the inner side of the furnace is lined with a refractory material.
7. A blast of hot air is sent into the furnace from the bottom. 
• At the same time, the mixture containing haematite falls from the top.
• Because of the heat, chemical reactions will take place. Let us see each of those reactions:
• The calcium carbonate (in the form of limestone) which is supplied along with the haematite, will decompose into calcium oxide and carbon dioxide. 
The equation is: CaCO(s) ➙ CaO (s) + CO(g)
8. The calcium oxide (CaO) thus formed will combine with silicon dioxide (SiO2). 
• This SiO2 is the main impurity. It is sand. 
• The reaction between sand and CaO converts the sand into calcium silicate.
• The equation is: CaO (s) + SiO(s) ➙ CaSiO(s)
• Thus the sand is removed. 
9. Now we are left with the iron oxide Fe2O3
• It will soon be reduced to iron. Let us see:
10. At the bottom of the furnace, coke combines with the oxygen. This oxygen is obtained from the hot blast of air. 
• The equation of the reaction is: C (s) + O(g) ➙ CO2 (g) + heat
• From the equation, we can see that it is an exothermic reaction. So the temperature rises upto 1800o C. 
• The CO2 thus produced rises to the upper parts of the furnace. It will get  reduced by coke. 
• The equation is: CO2 (g) + C (s) + heat ➙ 2CO (g)
11. The temperature in these upper parts is lower than the temperature at the bottom parts. This is because, the reaction here is endothermic. 
• Note that, the 'heat' is on the left side of the arrow. So there is an 'absorption of heat'
• The fig.13.7 above indicates that the lower parts are 'white hot'. While upper parts are 'red hot'. 
    ♦ 'White hot' is much hotter than 'red hot'.
    ♦ There is a gradation from white to red as we go upwards  
• The carbon monoxide reaches the middle portion of the furnace and reacts with the iron oxide.
• The iron oxide gets reduced to iron. 
• The equation is:  Fe2O (s) +3CO (g) ➙ 2Fe (s) + 3CO(g)
12. The iron thus formed moves downwards. 
• Due to the high temperatures in the lower parts, it will melt into liquid form. 
• This liquid gets collected at the bottom of the furnace. From there it can be taken out. This is shown in fig.13.7 above


Thus we successfully produce iron. Now we have to learn some technical terms involved in the above process.
■ The impurity in the ore is called gangue.
• See step (5) above. In our present case, sand (SiO2) is the gangue.
■ The chemical that is used to remove the gangue is called the flux.
• In step (8), we see that the calcium oxide (CaO) combines with sand to form calcium silicate.
• So in our present case, CaO is the flux
■ The product formed as a result of the reaction between gangue and flux is called the slag
• The only way to remove the sand is by converting it to 'another material'.   
• In step (8) we see that this 'another material' is calcium silicate (CaSiO3). It is formed as a result of the reaction between the gangue and the flux.
• So in our present case, CaSiOis the slag.
■ CaO is chosen as the flux because it is basic in nature. It will react with the gangue (SiO2) which is acidic in nature

13. The slag formed in our present case will melt due to the high temperature. So like the molten iron, it also becomes a liquid and gets collected at the bottom of the furnace
• But the two liquids do not mix together. This is because, the slag is lighter. 
• So it floats above the molten iron. So it can be removed easily. This is shown in the fig.13.7 above
• The formation of the separate 'slag layer' above the 'molten iron layer' has the following advantages:
    ♦ The two can be removed from the furnace easily
    ♦  Contact between molten iron and oxygen is avoided, thus preventing the formation of iron oxide.
14. The iron produced in this way has 4% carbon.
• That is., if we take 100 grams of this iron, 4 grams will be carbon
• This much carbon is not allowable. It will prevent the iron from acquiring it's unique properties. 
• This iron has other impurities also like manganese, silicon, phosphorus etc., 
• This iron is called pig iron. Images can be seen here. It has only limited use and is an intermediate product of the iron industry.
15. The pig iron is taken to another special furnace (The electric arc furnace is used in modern days).
• There, it is mixed with scrap iron and coke and again melted.
• The product obtained is called cast iron. It contains 3% carbon
• When molten cast iron cools and solidifies, there will be an increase in volume. 
• So the molten cast iron is poured into moulds to make various shapes. Some products can be seen here.
• The shapes thus obtained are very hard. But they will break if subjected to bending.
16. The cast iron can be purified further. 
• The product obtained will contain only 0.2 - 0.5% carbon. 
• It will also contain some traces of phosphorus and silicon. This is called wrought iron.
• Some products using wrought iron can be seen here.
17. So we can write:
Pig iron  Cast iron  Wrought iron

• We often hear the word steel. Words 'iron' and 'steel' are sometimes used interchangeably. 
• But they are not the same. Let us see the difference:
■ Iron is an element in the periodic table. It's symbol is Fe
• We try to make pure iron in the blast furnace. 
• But the product obtained contain some carbon and other impurities. 
• It is not possible to completely avoid the 'presence of some impurities'.
• However pure iron can be prepared in specially equipped labs
■ Steel is an alloy. 
• We know that alloy is:
    ♦ a combination of two or more metals
    ♦ or a combination of a metal and another element
• Steel is an alloy of 'the metal iron' and 'the element carbon'. 
• It should not contain any other element
• Also, the amount of carbon should not exceed 2%
• By varying the content of carbon within the 2%, steels having various properties can be obtained.
    ♦ Low carbon steels have carbon less than 0.3%
    ♦ Medium carbon steels have carbon from 0.3% to 0.6%
    ♦ High carbon steels have carbon more than 0.6%

Following are some of the processes done on steel:
■ Annealing:
• Heat the steel to high temperature
• And then allow it to cool slowly. 
• This will make the steel ready to be shaped into different forms
■ Hardening:
• Heat the steel to high temperature
• And then cool it rapidly by dipping in water or oil
• This will make the steel very hard. But it will be brittle
■ Tempering:
• Heat the hardened steel until it becomes blue in colour
• And then allow it to cool slowly.
• This will make the hardened steel less brittle, while maintaining the hardness 

We will now see 3 alloys in which iron is a component:
1. Name: Stainless steel
Components: Iron (Fe), Chromium (Cr), Nickel (Ni) and Carbon (C)
Properties: Strong, will not rust.
Uses: For the manufacture of utensils, parts of vehicles
2. Name: Alnico
Components: Iron (Fe), Nickel (Ni), Aluminium (Al) and Cobalt (Co)
Properties: Magnetic in nature
Uses: For the manufacture of permanent magnets
3. Name: Nichrome
Components: Iron (Fe), Nickel (Ni),  Chromium (Cr), and Carbon (C)
Properties: High resistance
Uses: For the manufacture of heating coils
■ If we examine the above alloys, we can note an interesting point:
• Stainless steel and nichrome have the same components. But their properties are different. 
• Why is that so?
AnsThe difference in properties is achieved by increasing or decreasing the quantity of each component of the alloys. For example:
• Take 100 grams of stainless steel
Let the amount of chromium contained in it be x1 grams
• Take 100 grams of nichrome
Let the amount of chromium contained in it be x2 grams
• Then x1 will not be equal to x2
• In other words, the 'percentage of chromium' in stainless steel and nichrome are different
• Same is applicable for the other components iron, nickel and carbon
■ We can make different alloys by:
• Combining appropriate metals and also by 
• Changing the percentage content of each metal or element

In the next section, we will see the industrial production of aluminium and copper. 

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